Australian TV
© Rex Features
It will be Bassingthwaighte's first TV appearance since giving birth.
Other presenters on the night will include Carmen Electra, Lara Bingle and Ruby Rose.
The awards ceremony will take place on November 7, and will feature live performances from Sia, the John Butler Trio, Birds of Tokyo, Angus and Julia Stone, and Megan Washington.
Mim and Liv Nervo will DJ at the awards, to be aired on Channel Ten.
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