The eight pairs will perform comical routines and enact spoofs to compete for the Hans Baliye trophy.
The two judges last worked together in 2000 on comedy Chal Mere Bhai, which co-starred Salman Khan and Sanjay Dutt.
Kapoor said: "On Indian television, we have a plethora of reality shows such as talent shows for dancing, singing, etc, but Hans Baliye gives a platform to real life couples to showcase their talent to a wider audience.
“Making people laugh is not an easy job. It requires a whole lot of dedication and hard work. I am looking forward to having a good time on the show.”