Dhupia will appear alongside the US singer on her TV show and offer her tips on how to wear a saree and other Indian fashion items.
She told The Times of India: "The producers got to know about me because of the US miniseries I did called Bollywood Hero.
"In keeping with my personality, I'll wear something Indo-Western for the show. But I know for sure that Jessica will be draped in a saree."
Dhupia will next be seen in Priyadarshan's De Dana Dan, which is scheduled for release on November 27.