Konami's compilation will bring enhanced versions of Metal Gear Solid 2: Sons of Liberty and Metal Gear Solid 3: Snake Eater to the Sony handheld.
The collection was previously released for PlayStation 3 and Xbox 360 with PSP original Metal Gear Solid: Peace Walker bundled in alongside the two games.
"The PlayStation Vita system will provide fans with an exciting new way to enjoy the Metal Gear Solid HD Collection," said Martin Schneider, general manager for Konami Digital.
"We're confident that users will be pleased with the new innovations Kojima Productions have implemented with the new PlayStation Vita iterations, offering a truly unique experience for this exciting new format."
Both games included in the pack will feature improved graphics, trophy support and controls optimised for the PS Vita hardware. Players will also be able to transfer data between the console and a PS3.
Metal Gear Solid HD Collection will be released for PS Vita this summer.
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Watch a trailer for the Xbox 360 and PlayStation 3 versions of Metal Gear Solid HD Collection below: