PAL users can purchase the game on June 29, two weeks after it launches in North America.
The game will include two classic titles from the series, Metal Gear Solid 2: Sons of Liberty and Metal Gear Solid 3: Snake Eater.
Both games feature improved graphics, trophy support and controls optimised for the PlayStation Vita hardware.
Using a combination of the Vita's touchscreen and touchpad capabilities, players can zoom into cutscenes, peek around corners, interrogate enemies, scroll through menus and perform quick attacks.
Players will also be able to transfer their save data between the handheld and a PS3.
The collection was previously released for PlayStation 3 and Xbox 360 with PSP original Metal Gear Solid: Peace Walker bundled in alongside the two games.
> Read Digital Spy's review of 'Metal Gear Solid HD Collection' for PS3
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Photo gallery - First images of Metal Gear Solid HD Collection on PS Vita below: