In addition to Daniel Craig once again stepping into the shoes of James Bond, famed Bond actors Michael Lonsdale and Richard Kiel will reprise their roles as infamous villains Hugo Drax and Jaws.
For the game's Skyfall mission, actor Rory Kinnear will continue his Quantum of Solace role as the voice of MI6 chief of staff Bill Tanner, while Naomie Harris will also voice her character Eve.
For the game's script, Activision secured GoldenEye writer Bruce Feirstein to tie together the missions from various Bond films into an overarching storyline. Die Another Day and Tomorrow Never Dies composer David Arnold will be joined by Hell on Wheels composer Kevin Kiner for the game's soundtrack.
Announced earlier this year, 007 Legends features missions spanning six different movies from the franchise's history, including upcoming release Skyfall.
The game is being developed by Eurocom, the team behind the recent GoldenEye 007: Reloaded release.
007 Legends will release on Xbox 360, PlayStation 3 and PC from October 16 in North America and October 19 in Europe.
Watch the trailer for 007 Legends below: