Developed by Eurocom, 007 Legends celebrates 50 years of James Bond and features levels based on classic films including Goldfinger, Moonraker and Licence to Kill.
Skyfall is the final mission in the first-person shooter, but although it is an "integral" part of the game's story, players will have to wait until November 9 before they can access it as free downloadable content - coinciding with the US release date of the film.
North American Xbox 360 owners, however, must wait until November 20 due to an exclusivity deal Sony has secured in that region.
Eurocom teased: "During the Skyfall mission, we visit two striking locations that have been faithfully recreated from the film, and we also feature some of the film's fantastic acting talent, including Daniel Craig as Bond."
In the UK, Skyfall launches in cinemas on October 26.
007 Legends is already out in North America and Europe.
> '007 Legends' opening cinematic released
> Games out this month: 10 biggest releases for October
Watch a trailer for 007 Legends below: