The Injustice: Gods Among Us Special Edition will be housed in a steelbook casing and features alternative Superman, Wonder Woman and Solomon Grundy character skins.
It also contains 20 additional missions set within the Red Son story arc, which sees Superman born and raised in the Soviet Union.
It joins the previously announced collector's edition, which comes with a statue, two issues of a brand new DC comic book series and three character skins.
The 25cm collectable figurine captures Batman and Wonder Woman in the midst of combat.
Announced last year, Injustice: Gods Among Us is said to have a deep original story, taking place in "a world where the lines between good and evil are blurred".
It features a growing list of heroes and villains from the DC Universe, including Batman, Harley Quinn, Superman, The Flash, Wonder Woman, Catwoman, Solomon Grundy, Nightwing, Cyborg, Green Arrow, Green Lantern, Bane, Deathstroke, Lex Luthor and The Joker.
NetherRealm is developing the title following 2011's success with Mortal Kombat. In 2008, the team also created Mortal Kombat vs DC Universe as Midway Games.
The developers have dropped the traditional three-round fighting system, opting instead for a "more cinematic" single-round system.
Injustice: Gods Among Us will be available on Xbox 360, PlayStation 3 and Wii U on April 16 in North America and April 19 in Europe.
Watch a gameplay trailer for Injustice: Gods Among Us below: