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The guitarist will be joined by Fun Lovin' Criminals frontman Huey Morgan, Radio 2 DJ Steve Lamacq and ex-footballer Dion Dublin for the one-off episode.
Colin Murray will host the Sony-nominated series as usual.
Fighting Talk is normally a sports-based comedy panel show, featuring sports stars and journalists debating the latest hot topics. The music special will still discuss the "key sporting questions", but will also feature a nod to the musical backgrounds of the guests.
The music special will air on Saturday, April 16 on 5 Live.
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