Movies
Rex Features
The set, scheduled for release on October 20, includes the first two films in the series - 1962's Dr. No and 1963's From Russia With Love.
The most recent franchise entry Casino Royale debuted on the high-definition format in March 2007 and is one of the highest-selling Blu-ray discs.
MGM's Eric Doctorow said: "With Quantum Of Solace on the horizon, Bond fever is building once again, and there is no better time to reintroduce these beloved films... to the more than 60 million HD-capable households worldwide."
Along with the first two Sean Connery films, Thunderball, Live And Let Die, For Your Eyes Only and Pierce Brosnan's final outing Die Another Day will be released this autumn.
The 22nd James Bond film Quantum Of Solace will hit cinemas on October 31.
Movie Reviews
'The Vow' reviewChanning Tatum tries to win back Rachel McAdams in romantic drama The Vow.
At the Movies
This Week's 5 Hottest Movie VideosTrailers for The Avengers and Spider-Man are among this week's highlights in film.
Movies Interviews
Daniel Radcliffe talks 'Woman in Black'The actor talks to Digital Spy about his first post-Potter outing.
Box Office Charts
'Chronicle' leads UK box officeSuperhero drama Chronicle leads the UK box office ahead of Journey 2.
