Movies
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Mickey Rourke, Penelope Cruz and Kate Winslet are also among the list of confirmed guests, reports PA.
The Curious Case Of Benjamin Button and Slumdog Millionaire lead the BAFTA nominations, with 11 nods apiece.
The award ceremony, hosted by Jonathan Ross, takes place at London's Royal Opera House. Daniel Craig, Emma Watson and Goldie Hawn are expected to present awards at the ceremony, as are Michael Sheen, Sharon Stone and Patrick Stewart.
The ceremony will be broadcast on BBC Two from 8pm before switching to BBC One for the final hour at 9pm.
Movie Reviews
'The Vow' reviewChanning Tatum tries to win back Rachel McAdams in romantic drama The Vow.
At the Movies
This Week's 5 Hottest Movie VideosTrailers for The Avengers and Spider-Man are among this week's highlights in film.
Movies Interviews
Daniel Radcliffe talks 'Woman in Black'The actor talks to Digital Spy about his first post-Potter outing.
Box Office Charts
'Chronicle' leads UK box officeSuperhero drama Chronicle leads the UK box office ahead of Journey 2.
