Mickey Rourke, Penelope Cruz and Kate Winslet are also among the list of confirmed guests, reports PA.
The Curious Case Of Benjamin Button and Slumdog Millionaire lead the BAFTA nominations, with 11 nods apiece.
The award ceremony, hosted by Jonathan Ross, takes place at London's Royal Opera House. Daniel Craig, Emma Watson and Goldie Hawn are expected to present awards at the ceremony, as are Michael Sheen, Sharon Stone and Patrick Stewart.
The ceremony will be broadcast on BBC Two from 8pm before switching to BBC One for the final hour at 9pm.