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Rex Features
Hotel Babylon star Michael Landes, Ugly Betty's Christopher Gorham, Carol Kane and Beau Bridges have also signed up for the indie project.
Milano's character is a confident, outgoing woman who meets two dream men - a struggling novelist (Gorham) and a wealthy ad executive (Landes) - and is forced to choose between them.
American Mormon's Daryn Tufts scripted and will direct the movie. Shooting begins this summer.
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Box Office Charts
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