The 'Set Fire To The Rain' singer let slip on the first edition of The Jonathan Ross Show that her next musical project would be a "theme", later becoming embarrassed when the 50-year-old host proceeded to reference the iconic spy series.
"I'm going back in the studio in November, fingers crossed," she stated. "Well, this is actually a theme, what I've got to do. Wow, that's really giving something away."
Blushing as Ross started humming the opening tune to previous James Bond instalments, Adele added: "No. It's a concept. One song."
Watch Adele in the video for 'Rolling In The Deep' below:
The London-born singer also claimed to have no "interest" in the celebrity lifestyle, and admitted to feeling homesick at this weekend's MTV Video Music Awards.
"I'm not very in touch with the fame side," she said. "I don't chase none of that and, to be honest, it doesn't interest me at all.
"I was at the VMAs the other day and it was a good night out but I felt pretty out of place and wished I was at home with my girlfriends."
Bond 23 will open in cinemas on October 26, 2012.
Watch the full interview with Adele on The Jonathan Ross Show at 9.45pm tonight on ITV1.
Watch Jack White and Alicia Keys in the video for 'Another Way To Die', the theme for the last James Bond movie Quantum Of Solace, below: