The pair will be appearing with This is 40's Megan Fox to honour the very best in film and television at the Beverly Hilton Hotel.
Previously announced presenters for the gala include eight-time Golden Globe winner Meryl Streep, George Clooney, Jennifer Lopez, Will Ferrell and Amanda Seyfried.
The Expendables 2's Jason Statham, Kristen Wiig, Jeremy Renner, Jennifer Garner and Smash actress Debra Messing are also slated to hand out trophies.
Amy Poehler and Tina Fey host this year's Golden Globe Awards for the very first time. They are taking over from Ricky Gervais, who helmed the last three ceremonies.
The 70th annual Golden Globes air from Los Angeles on Sunday (January 13) on NBC.
> Golden Globes nominations 2013: Movies list in full
> Golden Globes nominations 2013: TV list in full
Watch Tina Fey and Amy Poehler in a Golden Globes advert below (US only):