The track is the second single to be lifted from their Xenomania-produced album Yes, which debuted at number four earlier this month.
The two-track physical release will feature new song 'After The Event' and the Maxi CD will include new B-Sides 'The Former Enfant Terrible' and 'Up And Down'.
The download bundle will include a Richard X remix of album track 'The Way It Used To Be' and their recent medley from the Brit Awards, where the duo picked up the gong for outstanding contribution to music.
Pet Shop Boys kick off their world tour in Russia on June 10. They play Manchester Apollo on June 18 and London's O2 arena on June 19.