The song, called 'Take Control', will be released on November 1.
The track features a guest vocal from Alesha Dixon, contrary to recent reports which suggested that the grime collective had called in The Saturdays to feature on the single.
Roll Deep's last two singles, 'Good Times' and 'Green Light', topped the UK singles charts in April and August respectively.
'Take Control' will officially premiere on 1Xtra tonight at 7pm.
Their album, Winner Stays On, will be released on November 1.