It coincides with director Matthew Vaughn's decision to select the track for upcoming superhero movie X-Men: First Class.
In a statement, the band commented: "We're really happy to be asked back to perform at the National Movie Awards, it's always a great night.
"It'll be the first time that we perform our brand new song 'Love Love', so we're looking forward to getting out there and singing it live for everyone."
The National Movie Awards will be held next Wednesday at Wembley Arena in London, and also screened on ITV1 at the same time.
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