The single, due to be released next month, was selected by fans out of a number of choices from Rihanna's fifth studio album Loud.
Fans selected 'California King Bed' over 'Man Down', 'Cheers (Drink to That)', and 'Fading' in the Twitter poll.
Rihanna teased the video's premiere earlier this week.
The release will mark the singer's sixth single release from Loud in the US, as well as the album's fourth UK single release.
'California King Bed' will be officially available from June 12.
Watch the video for Rihanna's new single 'California King Bed' below: