Earlier this week, it was announced that fans would hear 12 specially-chosen tracks on the Lioness: Hidden Treasures collection.
The songs, recorded at various stages throughout Winehouse's life, have been picked by producer friends Mark Ronson and Salaam Remi. The album will be released on December 5.
It has now been confirmed that 'Our Day Will Come' will receive its radio debut on Radio 1's Chris Moyles breakfast show on Thursday morning.
Among the tracks included on the album is a demo version of 'Valerie', and 'Body and Soul', the 28-year-old's duet with Tony Bennett.
£1 from each sale of the LP will be donated to the Amy Winehouse Foundation, which was set up in her memory by father Mitch Winehouse.
> Amy Winehouse died from too much alcohol, coroner says
> Amy Winehouse memoir to be published by Mitch Winehouse next summer