The bands will be joined by The Saturdays and singer-songwriter Ed Sheeran for the second day of the Capital FM event on December 4.
Also on the bill at the festive concert, which will take place at London's O2 Arena, are Wretch 32 and 'Heaven' star Emeli Sandé.
It was previously announced that Rihanna, Olly Murs and The Wanted would perform during the first day of the Jingle Bell Ball on December 3.
Pixie Lott, Calvin Harris and Jason Derulo will also take to the stage on the first day of the event.
Tickets for the Saturday December 3 show are on sale now, while tickets for Sunday December 4 will go on sale on Monday (November 7).
It was recently confirmed that One Direction and JLS will feature on this year's X Factor charity single.
Watch One Direction's video for 'What makes You Beautiful' below: