The retailer announced this week that it would offer the LP free to US customers who signed up for a new mobile phone contract online or at any Best Buy or Best Buy Mobile location beginning on Monday, November 21.
Best Buy Senior VP and general manager of home entertainment Chris Homeister said in a statement: "Rihanna is one of the biggest stars in music today and we expect this to be a big release.
"Leveraging our Best Buy Mobile business on this offer sets us apart from the competition and gives consumers a great reason to visit Best Buy for their music and smartphone needs."
Rihanna recently unveiled a full stream of Talk That Talk online ahead of the album's release.
Earlier this week, it was announced that Rihanna will perform at The Grammy Nominations Concert Live!! - Countdown To Music's Biggest Night on CBS on November 30.
Watch Rihanna's video for 'We Found Love' below: