Brian Wilson, Mike Love, Al Jardine, Bruce Johnston and David Marks will perform together as The Beach Boys for the first time in more than 20 years for the ceremony.
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The Beach Boys will be joined by Maroon 5 and Foster the People for an all-star collaboration on the Grammy stage.
Jazz singer Diana Krall, The Civil Wars, former Eagle Joe Walsh and saxophonist Maceo Parker will also play during Sunday's awards show.
Diana Ross will not only receive the Grammys 'Lifetime Achievement Award', but she will present a coveted trophy as well.
Reba McEntire, Common, and Taraji P Henson have been added to the slate of Grammy presenters too.
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Katy Perry, Bruce Springsteen, Coldplay, Foo Fighters, Chris Brown and Adele are also among the performers for Sunday's gala.
LL Cool J hosts the 54th Annual Grammy Awards, which air live on February 12 from 8pm (ET/PT) on CBS.
> Grammy Awards 2012: Major nominees
Watch The Beach Boys perform 'Good Vibrations' below:
