The singer is seen giving a live performance of the track, called 'Love Interruption', which marks his debut solo release.
The song is backed by singer Ruby Amanfu, who enjoyed a brief solo career in 2003 with her hit single 'Sugah' and accompanying album Smoke & Honey.
The track marks the first cut from White's forthcoming album Blunderbuss, which will be released on April 23 via XL Recordings and Third Man Records.
'Love Interruption' was originally made available on January 30 as a free stream via his official website, while a vinyl version of the single featuring exclusive B-side 'Machine Gun Silhouette' was put out on February 7.
Third Man Records has also produced 300 limited edition Tri-Colour vinyl 45s of the single, which are available from a number of independent record stores now.
White recently announced that he will be performing at Radio 1's Hackney Weekend on June 23.
Watch the 'Love Interruption' music video below: