The singer will include 'Break These Chains' as the B-side to his debut single 'Seven Nation Army' on March 4.
'Break These Chains' was co-written by Collins along with Paul Meehan and Jamie Scott.
The X Factor finalist has worked with a range of producers for his self-titled debut album, including Brian Rawling, who has previously collaborated with Girls Aloud, Kylie Minogue and David Bowie.
As well as original tracks, the album will feature covers of White Stripes' 'Seven Nation Army', 'Your Love Is Lifting Me Higher' by Jackie Wilson and 'Tightrope' by Janelle Monae.
Marcus Collins will be released in the UK on March 12.
> Marcus Collins unveils debut single 'Seven Nation Army' - listen
> X Factor Marcus Collins wants Misha B, Adele collaborations
Listen to Marcus Collins's 'Break These Chains' below: