The singer will release 'Primadonna' as the trailer single from her second album Electra Heart, which will be released in the UK on April 30.
In support of her new track, Marina has debuted a stripped back rendition of the song which sees her perform with her band in a Victorian bathroom.
'Primadonna' is produced by Dr Luke, who has previously worked with Britney Spears and Katy Perry.
It will be officially available to download in the UK on April 22.
Marina and the Diamonds will embark on an eight-date headline tour of the UK in May in support of her new record Electra Heart.
> Marina and the Diamonds unveils 'Electra Heart' album cover, tracklist
Watch Marina and the Diamond perform an acoustic rendition of 'Primadonna' below: