The cover - which appears below - shows the singer in profile, exposing the tattoo on his neck.
The standard edition of the record - out June 12 and a day later in the US - features 14 tracks produced by the likes of Swedish House Mafia, Max Martin and Diplo, while the deluxe edition includes a further four songs.
Duets on the set are Rick Ross on 'Lemme See', Luke Steele on the title track and Pharrell Williams on 'Twisted'.
Usher recently debuted 'Lemme See' from the album, which is being offered as a free download when the record becomes available to pre-order on May 8.
The star's current single 'Climax' peaked at number four on the UK chart and number 20 in the US last month.
The Looking 4 Myself tracklisting appears below:
1. Cant Stop Wont Stop
4. I Care for U
5. Show Me
6. Lemme See ft. Rick Ross
7. Twisted ft. Pharrell
9. What Happened to U
10. Looking 4 Myself ft. Luke Steele
12. Lessons for the Lover
13. Sins of My Father
16. Say the Words
17. 2nd Round
18. Hot Thing
Watch the 'Climax' music video below: