The single-disc Iron Man: The Best of Black Sabbath is released on June 4 ahead of the band's live summer dates.
Featuring an identical tracklisting to 2009's Greatest Hits, 13 of the 14 tracks on the release are drawn from the band's first five albums Black Sabbath, Paranoid, Master of Reality, Black Sabbath Vol. 4 and Sabbath Bloody Sabbath, with the remaining - and most recent - song being the title track from 1978's Never Say Die!.
The full tracklisting of Iron Man: The Best of Black Sabbath is as follows:
2. 'Iron Man'
4. 'Fairies Wear Boots'
5. 'War Pigs'
6. 'Never Say Die'
7. 'Children of the Grave'
8. 'The Wizard'
10. 'Sweet Leaf'
11. 'Evil Woman (Don't Play Your Games)'
12. 'Sabbath Bloody Sabbath (Sabbath Bloody Sabbath)'
13. 'Black Sabbath (Black Sabbath)'
Watch Black Sabbath perform 'Paranoid' and 'Iron Man' for Beat Club in 1970 below:
Black Sabbath last month confirmed an intimate homecoming show at the O2 Academy Birmingham on Saturday, May 19.
The band play headline slots at this year's Download and Lollapalooza festivals, but were forced to cancel a number of dates on the European leg of their world tour after guitarist Tony Iommi was diagnosed with lymphoma.
The status of the group's original drummer Bill Ward in the reunion is not certain, following a contractual dispute with his bandmates Ozzy Osbourne, Iommi and Geezer Butler.