The track was recorded by a super-group consisting of Damien Dempsey, Bressie, Danny O'Reilly (Coronas) and The Dubliners (John Sheehan, Barney McKenna, Eamonn Campbell, Patsy Watchorn).
fun. have slipped to two with 'We Are Young', Jedward enter at three with their Euro 2012 cut 'Put the Green Cape On' and Carly Rae Jepsen is at four with 'Call Me Maybe'.
Rita Ora debuts at number 11 with 'R.I.P.', Rihanna's 'Where Have You Been' vaults up to number 13 from 32 and Calvin Harris is at 18 with 'Let's Go'.
Further down the chart, the Glee cast are at 29 with their take on the Florence + The Machine hit 'Shake It Out', while Mumford and Sons re-enter the chart at 35 with 'Little Lion Man'.
This week's Irish Top 10 is as follows:
1. (-) Various Artists: 'The Rocky Road to Poland'
2. (1) fun. feat. Janelle Monaé: 'We Are Young'
3. (-) Jedward: 'Put the Green Cape On'
4. (2) Carly Rae Jepsen: 'Call Me Maybe'
5. (3) Marina and the Diamonds: 'Primadonna'
6. (4) Nicki Minaj: 'Starships'
7. (5) Tulisa: 'Young'
8. (8) Maroon 5 ft. Wiz Khalifa: 'Payphone'
9. (7) Gotye feat. Kimbra: 'Somebody That I Used to Know'
10. (11) Jessie J ft. David Guetta: 'LaserLight'
Watch the official music video for 'The Rocky Road to Poland' below: