The songstress will reveal new material from her forthcoming Soul Sessions Vol 2 album. During the show, Stone will perform six new songs as well as tracks from her past records.
Stone's UK show can be watched on Wednesday, June 6 on MSN.com starting at 8.45pm GMT in Europeans territories.
Soul Sessions Vol 2 is a follow-up to Stone's 2003 debut album The Soul Sessions. Her last album was LP1 released in 2011 under her own label Stone'd Records.
Stone will release her first single 'While You're Out Looking For Sugar' from Soul Sessions Vol 2 on July 23.
Stone is expected to perform at the 2012 London Olympics ceremony, which has already booked Sir Paul McCartney to close the opening ceremony.
Watch the music video for Joss Stone's 'Super Duper Love' below: