Series 1 and the Christmas Special of the 2010 show follows Tulisa Contostavlos, Dappy and Fazer as the trio break through to the mainstream.
The DVD features the group on the T4 set, a near punch-up with Lethal Bizzle, Dappy going missing at an airport and other antics.
Celebrity appearances include spots from Mr Hudson and Rochelle Wiseman.
When it was first aired, the show attracted attention as Dappy admitted lying to the police about his name and address.
The series opener attracted 580k (6.2%) viewers on Channel 4 with an additional 56k (1.2%) watching on Channel 4 +1.
Being... N-Dubz is released on DVD on September 24.
Watch the trailer for the DVD series below: