The band will play a headline set at the Emirates Stadium on June 1 in support of their new albums ¡Uno!, ¡Dos! and ¡Tré!.
"We are at the most prolific and creative time in our lives," Green Day stated. "This is the best music we've ever written, and the songs just keep coming.
"Instead of making one album, we are making a three-album trilogy. Every song has the power and energy that represents Green Day on all emotional levels. We just can't help ourselves... We are going epic as f**k!"
Tickets for Green Day's show at London's Emirates Stadium go on sale from 9.30am on September 28.
Meanwhile, ¡Uno! will be released in the UK on September 24, while ¡Dos! follows on November 12 and ¡Tré! on January 14, 2013.
Watch Green Day perform 'Oh Love' at the Reading Festival below: