The band will release a double-disc set entitled Opposites in the UK on January 28, 2013.
The collection will come in two parts titled The Sand at the Core of Our Bones and The Land at the End of Our Toes.
It will be available as a CD/DVD and digital download, while a limited-edition box set will also be released.
The album will contain 20 tracks in total, with ten appearing on each disc.
The tracklist for Biffy Clyro's new album Opposites is as follows:
The Sand at the Core of Our Bones
1. 'Stingin' Belle'
2. 'Sounds Like Balloons'
4. 'The Joke's On Us'
5. 'Black Chandelier'
6. 'A Girl and His Cat'
8. 'The Fog'
9. 'Little Hospitals'
10. 'The Thaw'
The Land at the End of Our Toes
1. 'Different People'
2. 'Modern Magic Formula'
3. 'Spanish Radio'
4. 'Victory Over the Sun'
6. 'Trumpet or Tap'
8. 'Accident Without Emergency'
9. 'Woo Woo'
10. 'Picture a Knife Fight'
Watch the video for Biffy Clyro's new track 'Stingin' Belle' below: