The singer will release a cover of INXS's 1988 hit 'Never Tear Us Apart' on September 23, which has been recorded for the new John Lewis advertising campaign.
The accompanying artwork sees Faith saluting, while dressed in a metallic golden dress with a honeycomb-like bottom half.
"I have always loved this song and I feel honoured to sing it," Faith said of the track.
'Never Tear Us Apart' will be included on a repackaged version of Faith's second studio album Fall to Grace, which will be released on October 22.
The star will embark on a headline tour across the UK and Ireland to support the album, which starts in Dublin on January 21.
Watch the John Lewis advert which features Paloma Faith's 'Never Tear Us Apart' below: