Digital Spy was exclusively invited to watch the singer play three acoustic tracks at their headquarters in central London.
The former Voice contestant sang his new track 'Single Tear' as well as a cover of Steve Winwood's 'Higher Love', which first topped the charts in 1986.
James also took part in a live Twitter chat with Vevo prior to the show, answering fans' questions about his upcoming shows and debut album A Place I Go.
He tweeted after the performance: "The people @vevo_uk are too good to me. Letting me takeover their twitter #TylerJamesOnVEVO and they got me Starbucks and dominoes !!!!".
James releases A Place I Go on October 29, preceded by 'Single Tear' on October 22.
Watch the 'Single Tear' music video below: