The girl group will release Ten on November 26 to celebrate their 10th anniversary.
The retrospective will feature their debut hit 'Sound Of The Underground', along with popular singles 'The Promise', 'Biology' and 'Call The Shots'.
Ten will also feature four new tracks, including upcoming single 'Something New', 'On The Metro', 'Beautiful 'Cause You Love Me' and 'Every Now And Then'.
A two-disc edition will also be available and fans are able to vote for the ten songs they'd like to appear on the second CD via the group's official website.
Fans can choose from Girls Aloud's extensive collection of singles, B-sides and album tracks. Voting closes at midnight on October 21 and the selected tracks will be revealed one by one, every day at 10am from October 22.
Girls Aloud will embark on a 12-date headline tour of the UK in support of the new collection throughout February and March.
Their new single 'Something New' will be available to download from November 18.
The tracklist for Girls Aloud's new album Ten is as follows:
1. 'Something New'
2. 'The Promise'
3. 'The Loving Kind'
5. 'Sexy! No No No...'
6. 'Call The Shots'
7. 'Can't Speak French'
8. 'Something Kinda Ooooh'
10. 'The Show'
11. 'Love Machine'
12. 'I'll Stand By You'
14. 'No Good Advice'
15. 'Sound Of The Underground'
16. 'On The Metro'
17. 'Beautiful 'Cause You Love Me'
18. 'Every Now And Then'
Listen to Girls Aloud's new single 'Something New' below:
Girls Aloud's career in pictures:
Copyright: Rex Features ITV/Rex Features