Stars from the TV musical series covered the festive classic, which was originally released by Irving Berlin in 1942.
Listen to 'White Christmas' below:
The track is taken from their new Christmas LP Glee: The Music, The Christmas Album - Volume 3, which is available from December 10.
The ten-track record also includes renditions of 'Jingle Bell Rock', 'Silent Night', 'Happy Xmas (War Is Over)' and 'Hanukkah, Oh Hanukkah'.
The Glee cast have sold more than 43 million songs and over 12 million albums worldwide to date, scoring three consecutive number one albums in the States. The Christmas Album - Volume 3 marks the series's 19th LP.
The tracklisting for Glee: The Music, The Christmas Album - Volume 3, appears below. Pre-order the LP by clicking here.
1. Jingle Bell Rock
2. White Christmas
3. Have Yourself a Merry Little Christmas
4. Silent Night
5. Joy to the World
6. The First Noël
7. I'll Be Home for Christmas
8. Feliz Navidad
9. Hanukkah, Oh Hanukkah
10. Happy Xmas (War Is Over)