James Bond: Mark Kermode and Simon Mayo are Blofeld and Bond - video
The hosts of Kermode and Mayo's Film Review were made up as the iconic characters to promote an upcoming show.
A James Bond Special, with the BBC Philharmonic and Ren Harvieu, airs on Friday, September 14 on BBC Five Live and on the red button.
Kermode and Mayo's show last year went from an in-house BBC production to indie producer Somethin' Else after being put out for tender.
In 2010, Kermode was named the most trusted professional critic by the British public, despite winning just 3% of the vote.
After he ruled himself out of the running to replace Jonathan Ross on the BBC Film show, eventual presenter Claudia Winkleman admitted that she wanted Kermode to appear on the programme.