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The Friends star is going to speak out about the breakdown of her marriage to Pitt and about his current relationship with Jolie, claims the Daily Star.
A source said: "This book could ruin Angelina and Brad. Jen will prove that the pen really is mightier than the sword."
Jolie's brother James Haven has previously defended his sister's actions, insisting that she would never intentionally "hurt another woman".
Haven said: "Angie would always be careful when another woman’s feelings are concerned.
"She’d go out of her way to make sure there was no situation that would hurt another woman because of her, and I’m talking about a situation like one of Brad’s former partners or his ex-wife."
> In Pictures: 'Friends' then and now
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