Showbiz
Rex Features
The couple, who donated $6.8m (£4.1m) to good causes last year, were at the UNICEF charity ball in LA when they came face-to-face with the 67-year-old boxing legend.
An onlooker said that Jolie, 34, kissed Ali on the cheek during their encounter. "Ali was loving all the attention and seemed taken by Angelina too," he said.
Veteran producer Jerry Weintraub won the Danny Kaye Humanitarian Award at the event, held to honour those who make key contributions to UNICEF's mission to improve children's lives.
George Clooney, Matt Damon, Joan Collins and Cindy Crawford also attended, reports The Mirror.
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