The Kasabian musician will join the Rest of the World team for the charity event alongside the likes of Will Ferrell and Gerard Butler, as well as ex-Manchester United footballers Edwin Van der Sar and Ruud van Nistelrooy.
The event aims to raise money for children's charity UNICEF, with Robbie Williams captaining the England team, which also features the likes of Olly Murs and Teddy Sheringham.
James McAvoy and Mark Owen were the most recent additions to the squads.
Tickets are now on sale for Soccer Aid 2012 - call 0161 444 2012 or visit itv.com/socceraid.
Soccer Aid 2012's England v Rest of the World match will be played at Old Trafford on Sunday, May 27, airing on ITV1 from 8pm.
Kasabian recently stated that they are hopeful of cracking the US.
The Soccer Aid lineup so far is as follows:
Robbie Williams (Captain), Jason Isaacs, John Bishop, Paddy McGuinness, Olly Murs, Jonathan Wilkes, Ben Shephard, Jamie Theakston, Marvin Humes, Aston Merrygold, David Seaman, Jamie Redknapp, Teddy Sheringham, Mark Owen, Martin Keown and Bradley Walsh.
Rest of the World:
Michael Sheen (Captain), Will Ferrell, Gerard Butler, Mike Myers, Gordon Ramsay, James McAvoy, Edwin Van der Sar, Ruud Van Nistelrooy, Jaap Stam, Patrick Kielty, Roy Keane, Hernan Crespo, Sergio Pizzorno, Kenny Dalglish (Coach), Ian Rush (assistant).