In attendance alongside the film's cast and crew were His Royal Highness the Prince of Wales and Her Royal Highness the Duchess of Cornwall joining X Factor contestants, show judge Tulisa Contostavlos and host Dermot O'Leary.
Former Bond stars Sean Bean, Christopher Lee, Eunice Gayson and Shirley Eaton turned out for the premiere, with Olympic cyclist Victoria Pendleton and Paralympians Ellie Simmonds and Johnnie Peacock also in walking the red carpet.
But which celebrities were the fashion villains? And who successfully managed off the 'Bond girl' or 'dashing secret agent' style challenge? View our picture gallery below to find out!
Skyfall opens in UK cinemas on October 26 and November 9 in the US.
Watch a Skyfall preview clip below: