The actress and model sports a range of designs in the photoshoot for the fashion label.
The range includes a panelled bodice, '50s-inspired high-waisted briefs and underwear sets to suit various styles.
Most sets feature rich navy, with satin and lace used to add texture
Brook's favourite designs in the range include the lac-edged satin bra and knickers in navy and soft cream and the red satin lace body.
These pieces are designed to be "supportive, sculpting yet beautiful and sexy."
The range will be available in time for Valentine's Day from selected New Look stores and on the New Look website.
Prices for pieces in the collection, the follow-up to Brook's Christmas lingerie range and last year's Valentine's collection, start from £5.99.
Brook is reported to have reconciled with her ex-boyfriend Danny Cipriani after splitting from Thom Evans last month.
She recently described Katie Price as "unladylike" after the glamour model claimed to be "FLABergasted" by Brook's figure and suggesting that she had been "comfort eating".
"You're a heffer [sic], Kelly, but still a hot one," she concluded.
Kelly Brook and Thom Evans in swimwear - Photo gallery: