Showbiz
Rex Features
The former OC actor, 44, thinks Aniston would be perfect for a cameo on the FX legal series, which also stars Glenn Close.
He told OK!: "Jen would be fantastic! I'll have her people contact the show's people. It will happen! It'd be great."
The couple dated for three years before Aniston met former husband Brad Pitt in 1998. Donovan also starred as her boyfriend Joshua in the fourth season of Friends.
However, he said a reconciliation between the pair was unlikely, despite the fact that he has split with wife Corinne Kingsbury.
He said: "[Jennifer] likes top-notch hotels and luxury, and I like bed-and-breakfasts and riding my bike. That's the most shallow version of it, but it's indicative of our personalities."
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