As expected, Abersoch gang Maddie (Scarlett Bowman), Jono (Dylan Llewellyn) and Tilly (Lucy Dixon) are all back on the scene as regular characters, attending the college alongside established faces Jason, Bart and Sinead.
New characters George (Steven Roberts), Neil (Tosin Cole) and Callum (Laurie Duncan) are also in the mix of students, while Ruby and Esther aren't joining the college just yet but will continue to be involved with their friends' storylines.
Following yesterday's announcement, the Hollyoaks team have now released new pictures showing the group all together…
From left to right: Tilly, George, Sinead, Bart, Neil, Maddie, Callum and Jono.
George is billed as a "sharp-tongued fashionista", while Neil is Jono's best friend - who wrongly believes that he's a big hit with the ladies.
Callum, meanwhile, does manage to impress the girls at the sixth form, but he's hiding a dark secret…
Sinead is feeling nervous about joining the college, knowing that she'll have to see Jason and Bart every day after everything that went on between them recently.
On the night before lessons begin, tempers flare as Sinead attends Bart's warehouse party and makes a move on Maddie's new boyfriend. Could her actions spark a battle to become the sixth form's queen bee?
Hollyoaks' sixth formers become regulars from Monday, September 5 at 6.30pm on Channel 4.
> Read more Hollyoaks spoilers and news
Watch the recently-released video showing the group in action below: