A spokesman told the Herald Sun: "Jodi has put in a tremendous five years on Home and Away.
"It was a mutual decision for her to take this next step in her career. Jodi will always be part of the 7 family and has our love and support as she moves forward."
Last year, the actress was at the centre of a scandal after being reported missing in late May. On June 5, the 24-year-old star was reportedly found in a gangster's bedroom.
Gordon, who plays Martha in the long running soap, also split from Channel 7 television heir boyfriend, Ryan Stokes.