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The presenter and a panel of experts will replace stars' "fashion crimes" using video and pictures on A-Listers Unzipped.
Stylist Michael Schaeble, Grazia style director Paula Reed and others on the panel will decide how to dress each celebrity, then Klass will reveal which is her favourite.
Klass said she was "thrilled" with the new role: "It's amazing to have the ability to correct fashion faux pas through our unique CGI technology – I can’t wait for viewers to see it."
Jane Rogerson, UKTV's acting head of commissioning, said the series "heralds a new exciting type of series". She added: "We all have opinions on what celebrities should and shouldn’t have worn when we’re flicking through the magazines and A-Listers Unzipped taps into that, making compelling viewing."
Fans will also be able to makeover celebrities on the channel's website.
Fifteen half-hour episodes, produced in Canada by Cineflix for UKTV and E! Canada, will begin on March 25 at 11pm.
