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The popstar shot scenes with the Gavin & Stacey pair in London, reports The Mirror.
"The series promises to be comedy gold," commented a source. "Kylie was on cracking form while James and Mat were flirting like naughty school boys."
One of Minogue's scenes apparently saw her running after Horne while dressed in an evening gown and carrying shopping bags.
The comedy duo's new show will air on BBC Three in February.
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