TV
The sketch, which sees Brand dress up as Aniston and recite the phrase, "I'm fine, absolutely fine", will feature alongside new celebrity characters including Penelope Cruz and Gwyneth Paltrow.
Brand also revealed that she has dropped a few stars from the show.
"We shot a sketch with Kate Moss and Sadie Frost for Comic Relief so I sort of think once I've done Kate Moss to Kate Moss, there's not really anywhere else I can go with it so we decided to lay them to rest.
"And Kate Winslet seems to be doing her own sketches now judging by her performance at the Golden Globes. There's not much more to say about her, I'm just going to take a back seat and let her get on with it I think."
Katy Brand's Big Ass Show returns to ITV2 for its third series later this autumn.
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