TV
The ex-Take That star will be interviewed by the host of the BBC show and will also record a live performance for the programme when it is filmed on November 3.
Prior to the release of his comeback single 'Bodies', Williams appeared on ITV1 reality talent show The X Factor, with his performance of the track prompting a mixed response.
The singer's Trevor Horn-produced eighth studio album Reality Killed The Video Star is released on November 9.
Williams will appear on Friday Night With Jonathan Ross on November 6 at 10.35pm on BBC One.
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