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Rex Features
The singer will be the only guest on the programme on Monday, November 9 and will talk to panellists Kate Thornton, Denise Welch, Carol McGiffin and Sherrie Hewson.
Williams will also perform his upcoming single 'You Know Me', which is due for release on December 7.
Earlier this year, Williams reportedly said that he would have sex with McGiffin and fellow panellist Coleen Nolan if he were single.
The ex-Take That star recently appeared on The X Factor and has also lined up a performance on Friday Night With Jonathan Ross on November 6.
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